A novel route to organonitrites by Pd-catalyzed cross-coupling of sodium nitrite and potassium organotrifluoroborates.
نویسندگان
چکیده
Microwave irradiated palladium-catalyzed cross-coupling reaction of potassium styryltrifluoroborates and sodium nitrite gives the corresponding styryl nitrites in high yields. Potassium aryltrifluoroborates also furnish aryl nitrites under same reaction condition. This unprecedented cross-coupling is an interesting development and has the potential to lead to new nitration protocols.
منابع مشابه
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ورودعنوان ژورنال:
- Tetrahedron letters
دوره 54 9 شماره
صفحات -
تاریخ انتشار 2013